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Invar 36 · UNS K93600 · W. Nr. 1.3912 · GB 4J36 · Ni36 · Fe-Ni36

Invar 36 / 4J36 (K93600): composition, properties, fittings and flanges

Invar 36 (UNS K93600, W. Nr. 1.3912, Chinese 4J36) is a 36 % nickel iron-nickel alloy famous for its near-zero coefficient of thermal expansion: typically about 1.2 x 10⁻⁶ per °C between 20 °C and 100 °C, roughly one tenth that of carbon steel. The low expansion arises from the magnetostrictive balance of the face-centred cubic…

UNS
K93600
W. Nr.
1.3912
Density
8.11 g/cm³ (0.293 lb/in³)
Key strength
490 MPa / 71 ksi

Identification and standards

Grade identification
Short formInvar 36 · UNS K93600 · W. Nr. 1.3912 · GB 4J36 · Ni36 · Fe-Ni36
ClassificationControlled low thermal expansion nickel-iron alloy
UNSK93600
Werkstoff number1.3912
Material familyPrecision Alloys

Chemical composition

Invar 36 / 4J36 composition limits (weight percent)
ElementComposition (wt %)Why it is there
Nickel (Ni)35.0 - 37.0Sets the Invar near-zero expansion composition
Iron (Fe)BalanceMatrix
Manganese (Mn)0.60 max-
Silicon (Si)0.40 max-
Cobalt (Co)0.50 maxSlightly raises expansion if increased
Carbon (C)0.10 max-
Phosphorus (P)0.020 max-
Sulphur (S)0.020 max-
Chromium (Cr)0.25 max-
Copper (Cu)0.50 max-

Note Single figures are maximum limits unless shown as a range. Always confirm against the heat-specific EN 10204 3.1 certificate supplied with your order.

Mechanical properties

Invar 36 / 4J36 - mechanical properties (stated condition)
Tensile strength, min (annealed)490 MPa / 71 ksi
0.2 % yield strength, min240 MPa / 35 ksi
Elongation in 2 in, min30 %
Typical hardness, annealed130 - 180 HB
Curie temperatureAbout 230 °C
Modulus of elasticity141 GPa (20.5 x 10⁶ psi)

Warning Values depend on product form, section thickness and heat treatment. Larger sections generally achieve lower strength than thin product; always design against the applicable code allowable stress rather than these figures.

Physical properties

Invar 36 / 4J36 - physical constants
Density8.11 g/cm³ (0.293 lb/in³)
Melting range1425 - 1460 °C (2600 - 2660 °F)
Thermal conductivity at 20 °C10.5 W/m·K
Mean CTE, 20-100 °C1.2 x 10⁻⁶ /°C
Mean CTE, 20-300 °CAbout 5.0 x 10⁻⁶ /°C
Electrical resistivity at 20 °C0.80 µΩ·m

Specifications by product form

Invar 36 / 4J36 - governing specifications
Bar / rodASTM F1684, ASTM B753 where applicable
Plate / sheet / stripASTM F1684, GB/T 15018 where applicable
Seamless tubeSupplied to drawing or customer specification
ForgingsTo drawing, EN 10204 3.1 certified
Welding consumablesMatching Invar filler or high-nickel filler depending on joint duty
UNS / EN / ChinaUNS K93600 · EN Ni36 · W. Nr. 1.3912 · GB 4J36

Product forms available

Hangbo supplies this grade in the following forms. Sizes outside the listed range can often be produced to order.

  • Wire and rod for electronic components
  • Forged blocks and rings for tooling
  • Machined components to drawing
  • Composite lay-up tooling and fixture plates

Typical applications

  • LNG carrier membrane tanks, cryogenic piping supports and transfer line components
  • Aerospace composite bonding and lay-up tooling where expansion must match carbon fibre
  • Precision instruments, optical benches, lasers and metrology frames
  • Electronic components, lead frames, shadow masks and resonator cavities
  • Thermostat bimetal strip and temperature compensation devices
  • Clock pendulums, seismic devices and scientific apparatus

Welding, forming and machining

Heat treatment
Anneal at 830-870 °C then air cool to stabilise dimensions, followed by a low temperature artificial age around 315 °C for 1 hour and slow cool. This stabilisation is essential for maximum dimensional stability.
Welding
Weld by GTAW with matching Invar filler metal and low heat input. Excessive heat input or dilution with high expansion alloys destroys the Invar effect locally.
Machining
Invar is gummy and work hardens; use sharp tools with positive rake, moderate speeds and generous cutting fluid to avoid surface tearing.
Design limit
Do not rely on the low expansion behaviour above about 230 °C, the Curie point, because the magnetic balance that causes the Invar effect no longer applies.

Buy Invar 36 / 4J36 from Hangbo

Material is supplied with full heat-number traceability, solution annealing or ageing performed under calibrated furnace control, and an EN 10204 3.1 certificate covering chemical analysis, mechanical properties, heat treatment records and the agreed NDT scope. Positive material identification and third party inspection and test reports from SGS are available for critical service.

Request a quotation for Invar 36 / 4J36

Invar 36 / 4J36 frequently asked questions

What does Invar 36 actually mean?
Invar refers to the invariance of the alloy's dimensions with temperature. With about 36 % nickel the normal thermal expansion of the iron lattice is offset by magnetostrictive contraction, giving a near-net-zero expansion coefficient between roughly -80 °C and 100 °C.
Is 4J36 the same as Invar 36?
4J36 is the Chinese GB designation for the K93600 Invar 36 composition. Chemistry and expansion behaviour are equivalent, and Hangbo supplies material to either standard.
Can Invar 36 be used at cryogenic temperature?
Yes. It is widely used in LNG containment because it retains ductility and toughness down to -196 °C while keeping predictable expansion behaviour.
Why does Invar need an artificial ageing treatment?
A low temperature artificial age stabilises the lattice and removes the slow drift in dimensions that occurs during early service, giving repeatable expansion values.

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