Technical knowledge
Titanium Grade 2 for seawater, chlorine and desalination piping
Why titanium Grade 2 is effectively immune to seawater corrosion, where it is used in desalination and chlor alkali plants, and the limits around velocity, crevices, dry chlorine and galvanic coupling that must be respected.

Why titanium behaves differently from stainless steel
Titanium forms a titanium dioxide film that is stable and self healing in oxidising environments containing water. Chloride does not break that film, so pitting and crevice corrosion in seawater are not the governing failure modes. Grade 2 is unalloyed, which gives excellent formability and weldability, with strength supplied by the section rather than by the alloy.
Composition and properties
| Item | Value | Significance |
|---|---|---|
| Titanium | Balance, about 99 % | Base metal |
| Oxygen | 0.25 % maximum | Strength control |
| Iron | 0.30 % maximum | Impurity control |
| Density | 4.51 g/cm3 | About 45 % lighter than steel |
| Minimum yield strength | About 275 MPa | Comparable with 316L |
| Thermal conductivity | Low, about a fifth of steel | Affects heat transfer design |
| Typical specification | ASTM B381 for flanges, B363 for fittings | Procurement reference |
Where Grade 2 is the standard answer
- Desalination heat exchanger tubing and water boxes. Immune to seawater and to chlorination.
- Seawater cooling and firewater systems. No corrosion allowance needed and tolerant of high velocity.
- Chlor alkali and chlorine dioxide plants. Wet chlorine service at controlled conditions.
- Offshore topside piping. Weight saving and zero maintenance over the plant life.
Limits that must be respected
- Dry chlorine is dangerous. Titanium reacts violently with dry chlorine gas. A minimum water content is required for safe use.
- Hydrofluoric acid dissolves the oxide. Avoid fluoride containing streams or control them very carefully.
- Galvanic coupling. Titanium is highly noble. Coupling it to carbon steel or aluminium accelerates corrosion of those metals; use isolation or a compatible design.
- Crevices at high temperature. Above roughly 80 C in tight crevices, Grade 2 can suffer crevice attack; Grade 7 or Grade 12 is used where that risk is real.
- Fire risk. Titanium can ignite in certain oxidising environments; review the safety case for oxygen and nitrogen dioxide service.
Questions about this topic
Does titanium corrode in seawater at all?
Why is titanium more expensive but still chosen?
Can titanium flanges be bolted to carbon steel flanges?
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